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tech
More
Than You Ever Wanted to Know About Motor
Oil
By Ed
Hackett edh@maxey.unr.edu
Edits:
-
v1.0 First there
was 1.0. Before that there was
darkness.
-
v1.1 Change in
description of viscosity.
-
v1.2 Updated info
on AMSOIL (courtesy of Morgan
McArthur
mgn@inel.gov)
Choosing
the best motor oil is a topic that comes
up frequently in discussions between
motoheads, whether they are talking
about motorcycle s or cars. The
following article is intended to help
you make a choice based on more than the
advertising hype.
Oil companies provide data on their oils
most often referred to as "typical
inspection data". This is an average of
the actual physical and a few common
chemical properties of their oils. This
information is available to the public
through their distributors or by writing
or calling the company directly. I have
compiled a list of the most popular,
premium oils so that a ready comparison
can be made. If your favorite oil is not
on the list get the data from the
distributor and use what I have as a
data base.
This article is going to look at six of
the most important properties of a motor
oil readily available to the public:
viscosity, viscosity index (VI), flash
point, pour point, % sulfated ash, and %
zinc.
Viscosity is a measure of the "flowability"
of an oil. More specifically, it is the
property of an oil to develop and
maintain a certain amount of shearing
stress dependent on flow, and then to
offer continued resistance to flow.
Thicker oils generally have a higher
viscosity, and thinner oils a lower
viscosity. This is the most important
property for an engine. An oil with too
low a viscosity can shear and lose film
strength at high temperatures. An oil
with too high a viscosity may not pump
to the proper parts at low temperatures
and the film may tear at high rpm.
The weights given on oils are arbitrary
numbers assigned by the S.A.E. (Society
of Automotive Engineers). These numbers
correspond to "real" viscosity, as
measured by several accepted techniques.
These measurements are taken at specific
temperatures. Oils that fall into a
certain range are designated 5, 10, 20,
30, 40, 50 by the S.A.E. The W means the
oil meets specifications for viscosity
at 0 F and is therefore suitable for
Winter use.
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Multi viscosity oils
work like this: Polymers are added to a light base
(5W, 10W, 20W), which prevent the oil from thinning
as much as it warms up. At cold temperatures the
polymers are coiled up and allow the oil to flow as
their low numbers indicate. As the oil warms up the
polymers begin to unwind into long chains that
prevent the oil from thinning as much as it normally
would. The result is that at 100 degrees C the oil
has thinned only as much as the higher viscosity
number indicates. Another way of looking at multi-vis
oils is to think of a 20W-50 as a 20 weight oil that
will not thin more than a 50 weight would when hot.
Multi viscosity oils are
one of the great improvements in oils, but they
should be chosen wisely. Always use a multi grade
with the narrowest span of viscosity that is
appropriate for the temperatures you are going to
encounter. In the winter base your decision on the
lowest temperature you will encounter, in the
summer, the highest temperature you expect. The
polymers can shear and burn forming deposits that
can cause ring sticking and other problems. 10W-40
and 5W-30 require a lot of polymers (synthetics
excluded) to achieve that range. This has caused
problems in diesel engines, but fewer polymers are
better for all engines. The wide viscosity range
oils, in general, are more prone to viscosity and
thermal breakdown due to the high polymer content.
It is the oil that lubricates, not the additives.
Oils that can do their job with the fewest additives
are the best. |
Very few manufactures recommend 10W-40
any more, and some threaten to void
warranties if it is used. It was not
included in this article for that
reason. 20W-50 is the same 30 point
spread, but because it starts with a
heavier base it requires less viscosity
index improvers (polymers) to do the
job. AMSOIL can formulate their 10W-30
and 15W-40 with no viscosity index
improvers but uses some in the 10W-40
and 5W-30. Mobil 1 uses no viscosity
improvers in their 5W-30, and I assume
the new 10W-30. Follow your
manufacturer's recommendations as to
which weights are appropriate for your
vehicle.
Viscosity Index is an empirical number
indicating the rate o f change in
viscosity of an oil within a given
temperature range. Higher numbers
indicate a low change, lower numbers
indicate a relatively large change. The
higher the number the better. This is
one major property of an oil that keeps
your bearings happy. These numbers can
only be compared within a viscosity
range. It is not an indication of how
well the oil resists thermal breakdown.
Flash point is the temperature at which
an oil gives off vapors that can be
ignited with a flame held over the oil.
The lower the flash point the greater
tendency for the oil to suffer
vaporization loss at high temperatures
and to burn off on hot cylinder walls
and pistons. The flash point can be an
indicator of the quality of the base
stock used. The higher the flash point
the better. 400 F is the minimum to
prevent possible high consumption. Flash
point is in degrees F.
Pour point is 5 degrees F above the
point at which a chilled oil shows no
movement at the surface for 5 seconds
when inclined. This measur ement is
especially important for oils used in
the winter. A borderline pumping
temperature is given by some
manufacturers. This is the temperature
at which the oil will pump and maintain
adequate oil pressure. This was not
given by a lot of the manufacturers, but
seems to be about 20 degrees F above the
pour point. The lower the pour point the
better. Pour point is in degrees F.
% sulfated ash is how much solid
material is left when the oil burns. A
high ash content will tend to form more
sludge and deposits in the engine. Low
ash content also seems to promote long
valve life. Look for oils with a low ash
content.
% zinc is the amount of zinc used as an
extreme pressure, anti-wear additive.
The zinc is only used when there is
actual metal to metal contact in the
engine. Hopefully the oil will do its
job and this will rarely occur, but if
it does, the zinc compounds react with
the metal to prevent scuffing and wear.
A level of .11% is enough to protect an
automobile engine for the extended oil
drain interval, under normal use. Those
of you with high revving, air cooled
motorcycles or turbo charged cars or
bikes might want to look at the oils
with the higher zinc content. More
doesn't give you better protection, it
gives you longer protection if the rate
of metal to metal contact is abnormally
high. High zinc content can lead to
deposit formation and plug fouling.
The Data: Listed alphabetically ---
indicates the data was not available
|
Brand |
VI |
Flash |
Pour |
%
Ash |
%
Zinc |
Brand |
VI |
Flash |
Pour |
%
Ash |
%
Zinc |
|
20W-50 |
|
|
|
|
|
20W-40 |
|
|
|
|
|
|
AMSOIL (old) |
136 |
482 |
-38 |
<.5
|
--- |
AMSOIL |
124 |
500 |
-49 |
--- |
--- |
|
AMSOIL (new) |
157 |
507 |
-44 |
--- |
--- |
Castrol Multi-Grade |
110 |
440 |
-15 |
.85 |
.12 |
|
Castrol GTX |
122 |
440 |
-15 |
.85 |
.12 |
Quaker State |
121 |
415 |
-15 |
.9 |
--- |
|
Exxon High Performance |
119 |
419 |
-13 |
.70 |
.11 |
15W-50 |
|
|
|
|
|
|
Havoline Formula 3 |
125 |
465 |
-30 |
1.0 |
--- |
Chevron |
204 |
415 |
-18 |
.96 |
.11 |
|
Kendall GT-1 |
129 |
390 |
-25 |
1.0 |
.16 |
Mobil 1 |
170 |
470 |
-55 |
--- |
--- |
|
Pennzoil GT Perf. |
120 |
460 |
-10 |
.9 |
--- |
Mystic JT8 |
144 |
420 |
-20 |
1.7 |
.15 |
|
Quaker State Dlx. |
155 |
430 |
-25 |
.9 |
--- |
Red
Line |
152 |
503 |
-49 |
--- |
--- |
|
Red
Line |
150 |
503 |
-49 |
--- |
--- |
5W-50 |
|
|
|
|
|
|
Shell Truck Guard |
130 |
450 |
-15 |
1.0 |
.15 |
Castrol Syntec |
180 |
437 |
-45 |
1.2 |
.10 |
|
Spectro Golden 4 |
174 |
440 |
-35 |
--- |
.15 |
Quaker State Synquest |
173 |
457 |
-76 |
--- |
--- |
|
Spectro Golden M.G. |
174 |
440 |
-35 |
--- |
.13 |
Pennzoil Performax |
176 |
--- |
-69
|
--- |
--- |
|
Unocal |
121 |
432 |
-11 |
.74 |
.12 |
5W-40 |
|
|
|
|
|
|
Valvoline All Climate |
125 |
430 |
-10 |
1.0 |
.11 |
Havoline |
170 |
450 |
-40 |
1.4 |
--- |
|
Valvoline Turbo |
140 |
440 |
-10 |
.99 |
.13 |
10W-30 |
|
|
|
|
|
|
Valvoline Race |
140 |
425 |
-10 |
1.2 |
.20 |
AMSOIL (old) |
142 |
480 |
-70 |
<.5 |
--- |
|
Valvoline Synthetic |
146 |
465 |
-40 |
<1.5 |
.12 |
AMSOIL (new) |
162 |
520 |
-76 |
--- |
--- |
|
15W-40 |
|
|
|
|
|
Castrol GTX |
140 |
415 |
-33 |
.85 |
.12 |
|
AMSOIL (old) |
135 |
460 |
-38 |
<.5 |
--- |
Chevron Supreme |
150 |
401 |
-26 |
.96 |
.11 |
|
AMSOIL (new) |
164 |
462 |
-49 |
--- |
--- |
Exxon Superflo Hi Perf |
135 |
392 |
-22 |
.70 |
.11 |
|
Castrol |
134 |
415 |
-15 |
1.3 |
.14 |
Exxon Superflo Supreme |
133 |
400 |
-31 |
.85 |
.13 |
|
Chevron Delo 400 |
136 |
421 |
-27 |
1.0 |
--- |
Havoline Formula 3 |
139 |
430 |
-30 |
1.0 |
--- |
|
Exxon XD3 |
--- |
417 |
-11 |
.9 |
.14 |
Kendall GT-1 |
139 |
390 |
-25 |
1.0 |
.16 |
|
Exxon XD3 Extra |
135 |
399 |
-11 |
.95 |
.13 |
Mobil 1 |
160 |
450 |
-65 |
--- |
--- |
|
Kendall GT-1 |
135 |
410 |
-25 |
1.0 |
.16 |
Pennzoil PLZ Turbo |
140 |
410 |
-27 |
1.0 |
--- |
|
Mystic JT8 |
142 |
440 |
-20 |
1.7 |
.15 |
Quaker State |
156 |
410 |
-30 |
.9 |
--- |
|
Red
Line |
149 |
495 |
-40 |
--- |
--- |
Red
Line |
139 |
475 |
-40 |
--- |
--- |
|
Shell Rotella w/XLA |
146 |
410 |
-25 |
1.0 |
.13 |
Shell Fire and Ice |
155 |
410 |
-35 |
.9 |
.12 |
|
Valvoline All Fleet |
140 |
--- |
-10 |
1.0 |
.15 |
Shell Super 2000 |
155 |
410 |
-35 |
1.0 |
.13 |
|
Valvoline Turbo |
140 |
420 |
-10 |
.99 |
.13 |
Shell Truck Guard |
155 |
405 |
-35 |
1.0 |
.15 |
|
5W-30 |
|
|
|
|
|
Spectro Golden M.G. |
175 |
405 |
-40 |
--- |
--- |
|
AMSOIL (old) |
168 |
480 |
-76 |
<.5 |
--- |
Unocal Super |
153 |
428 |
-33 |
.92 |
.12
|
|
AMSOIL (new) |
186 |
464 |
-76 |
--- |
--- |
Valvoline All Climate |
130 |
410 |
-26 |
1.0 |
.11 |
|
Castrol GTX |
156 |
400 |
-35 |
.80 |
.12 |
Valvoline Turbo |
135 |
410 |
-26 |
.99 |
.13 |
|
Chevron Supreme |
202? |
354 |
-46 |
.96 |
.11 |
Valvoline Race< /TD>
|
130 |
410 |
-26 |
1.2 |
.20 |
|
Chevron Supreme Synt. |
165 |
446 |
-72 |
1.1 |
.12 |
Valvoline Synthetic |
140 |
450 |
-40 |
<1.5 |
.12 |
|
Exxon Superflow HP |
148 |
392 |
-22 |
.70 |
.11 |
|
Havoline Formula 3 |
158 |
420 |
-40 |
1.0 |
--- |
|
Mystic JT8 |
161 |
390 |
-25
|
.95 |
.1 |
|
Quaker State |
165 |
405 |
-35 |
.9 |
--- |
|
Red
Line |
151 |
455 |
-49 |
--- |
--- |
|
Shell Fire and Ice |
167 |
405 |
-35 |
.9 |
.12 |
|
Unocal |
151 |
414 |
-33 |
.81 |
.12 |
|
Valvoline All Climate |
135 |
405 |
-40 |
1.0 |
.11 |
|
Valvol ine Turbo |
158 |
405 |
-40 |
.99 |
.13 |
|
Valvoline Synthetic |
160 |
435 |
-40 |
<1.5 |
.12 |
All of the oils above meet current SG/CD
ratings and all vehicle manufacture's
warranty requirements in the proper
viscosity. All are "good enough", but
those with the better numbers are icing
on the cake.
The synthetics offer the only truly
significant differences, due to their
superior high temperature oxidation
resistance, high film strength, very low
tendency to form deposits, stable
viscosity base, and low temperature flow
characteristics. Synthetics are superior
lubricants compared to traditional
petroleum oils. You will have to decide
if their high cost is justified in your
application.
The extended oil drain intervals given
by the vehicle manufacturers (typically
7500 miles) and synthetic oil companies
(up to 25,000 miles) are for what is
called normal service. Normal service is
defined as the engine at normal
operating temperature, at highway
speeds, and in a dust free environment.
Stop and go, city driving, trips of less
than 10 miles, or extreme heat or cold
puts the oil change interval into the
severe service category, which is 3000
miles for most vehicles. Synthetics can
be run two to three times the mileage of
petroleum oils with no problems. They do
not react to combustion and combustion
by-products to the extent that the dead
dinosaur juice does. The longer drain
intervals possible help take the bite
out of the higher cost of the
synthetics. If your car or bike is still
under warranty you will have to stick to
the recommended drain intervals. These
are set for petroleum oils and the
manufacturers make no official allowance
for the use of synthetics.
Oil additives should not be used. The
oil companies have gone to great lengths
to develop an additive package that
meets the vehicle's requirements. Some
of these additives are synergistic, that
is the effect of two additives together
is greater than the effect of each
acting separately. If you add anything
to the oil you may upset this balance
and prevent the oil from performing to
specification.
The numbers above are not, by any means,
all there is to determining what makes a
top quality oil. The exact base stock
used, the type, quality, and quantity of
additives used are very important. The
given data combined with the
manufacturer's claims, your personal
experience, and the reputation of the
oil among others who use it should help
you make an informed choice.
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not provide all necessary or relevant information. Applicable
local laws and regulations may vary and should be checked before
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information.
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